How much current do you need?
Attaching a negative voltage doubler will give the wrong voltage, and not play well with most switching regulators.
Have you considered a multi-winding inductor? A pair of dual inductors, primaries wired in parallel, secondaries wired for complementary outputs, will do. (This is a SEPIC configuration, with an extra output that happens to be negative. Coupling caps can be used to improve performance, but mind how the negative output is wired!)
Hmm, I did this a few months ago actually, a board that needed voltages for a traditional analog front end, meanwhile everything else was 5V supply. So there was a 500mA boost regulator and dual inductors wired in this way, to give about 30mA available at the 15V outputs.
Note that, since the outputs are coupled through inductors, the cross-regulation isn't great. This was wired for +15V regulation, and the -15V does whatever; I got down to -16.5V with full load on +15 and none on -15, and the opposite (about -13V) with full load on -15 and none on +15. That's perfectly adequate for analog purposes, but if you were hoping for something more accurate, you may consider making extra (18-20V?) and regulating it down, or using two independent (switching) regulators period.
Tim