You want a TVS that does nothing at 20V (or 24V) yet clamps below the point of damage to the controller. SMD marking code SYTB I couldn't find, it might be an LM2841 max. 45V input. So a 22A or 27A TVS is OK.
Notice app. note 88 also shows adding a bulk capacitance 47uF 35V works very well.
I would put in both the TVS and capacitor, like this schematic.
The Quicko "STM32 T12" controller, I notice the ads on Ali are no longer showing this controller in the T12-943 stations.
It seems to be replaced by the "T12-952 STC OLED" which is back to using a linear voltage reg.