Thanks, I ended up purchasing these instead:
https://www.digikey.com/en/products/detail/t-global-technology/TG-A6200-30-30-1-5/11617042
The resistors are 3x7mm, with the leads less than 0.5mm above the resistor body. Isn't 5mm at this scale too thick?
These "thermal pads", "silpads", "gap pads" are manufactured in wide range of thicknesses, and while they are decent thermal conductors compared to air, they still suck compared to metal. So you want to keep them as thin as possible. But sometimes you need something like 5mm. These thick products are usually softer, too, so they can conform to the components.
Now if you can place this to underside of the board in area where there are no components or TH legs at all, and you can couple it to a metal surface like chassis, I recommend approx. 0.5 mm thickness. This is thick enough to smooth out the tiny gaps and bumps in PCB / enclosure surfaces or compensate for slightly angled mounting by squeezing out and filling the gap; yet not too thick to hinder heat transfer.
Sometimes you actually use this stuff on component side (with thin as possible components of course), and then you might want to use those thicker variants, up to 5mm.
But if you have two smooth surfaces like PCB + enclosure separated by 5.0mm, do not use 5-6mm thick thermal pad, instead use a 4.5mm thick aluminum block + 0.7mm thick thermal pad or so. Best to have mounting holes near to apply decent pressure.
The thicker it is, the more it pays of to select higher possible thermal conductivity. Best products are around 15 W/(mK).
Also note voltage ratings. If you are working with mains voltages and need isolation, you may need glassfiber reinforced and certified silpads. The reinforcement compromises thermal conductivity, you may have to use one rated for just 3-4 W/(mK) and then add some thickness.
For comparison, aluminum is around 200W/(mK).