Yes, I saw the no power and mains use on the Speakon connectors. This may be an operating environment thing though - you don't want the possibility of connecting DC power or mains into a speaker cabinet. I really don't know though, they have pretty rugged contacts, in addition to being cheap to replace.
The no breaking on the Powercon is potentially an issue though.
Generally, looking at switch / relay contact ratings, you normally see specifications of 24V DC / 240V AC to account for the lack of zero-crossings. I think It's going to be tough to find an easily insertable connector that is officially rated for hot making (contact weld) / breaking (arc) high current DC, even the vehicle ones. One thought is that the connector is only likely to be removed once the battery is charged, and so is only carrying minimal current.