I actually ordered free samples of the LT3080, TLC2272 and I just need to order the LT1009. So far the only thing I've bought is the LM334 and the discrete components. I'm also going to need to buy a two 10 turn pots because I can't seem to find any place that would give out a free sample of such an expensive part. Linear Technology, NS, and TI, and others will give free samples so don't hesitate to try them out. Don't overdo it though because it's kind of rude. I only ordered how much I needed, not going to abuse the system. If I like it I might try altering the design a bit and see what I can do by buying the parts.
Anyway, free samples are great. Have at it.