That's probably fine. Keep in mind you can parallel two strands to get approx. 3 AWG's lower equivalent cross section, so one every 6 is reasonable (so, 18, 24, 30, 36?). You might want very fine wire for litz, but you might be better off buying it straight up and as needed (
https://www.ebay.com/str/elecmall is a source I've used, and there are many others) since it's a PITA to make, and won't be "served" (wrapped).
The coarser sizes are more for power and frequency; the use at high frequencies might be more for helical resonators or high-Q coils, and of course power amps (tuning or RFC); otherwise, just power, at lower frequencies probably in combination with ferrite or powder cores for SMPS use (where skin effect may or may not matter, depending on use: mainly that skin effect and core loss are deprioritized in deep CCM, but high ripple fraction or DCM, and transformer duty, benefit from finer stranding and lower core loss materials).
Which, for SMPS use, a selection of E, P, T or other core shapes might not be a bad idea. But if you're doing mostly low level RF projects, just sticking to small toroids (in materials such as #2, #8, #43, etc.) and binocular cores might be more important.
Wirewrap wire in the 26-30AWG range might also be of interest. Insulation is thicker than magnet wire (obviously), giving a diff pair impedance closer to 100Ω, and more isolation voltage which may be of interest for diverse application (isolated gate drive for example). Or CAT5/etc. style cable, chopped up into pairs, a bit thicker (24AWG usually) but the insulation has nice low loss.
Tim