Eh, for normal quick charging, 1.45V is right around where you expect the peak to be, according to the book on battery charging that I was reading last night! But you’d only do that when using actual peak detection, which isn’t really what’s being done here.
OP, if you’re not going to implement a proper charger, why not just make it an fixed constant-current trickle charger at C/50-C/30 or so?