Do not blow a cent on software. There's some seriously good software around that's for free or has a free license that is good for beginners.
Here's a small list:
(1) Eagle - Eagle has been the de-facto standard for hobbyists and beginners. It is available for free with some limitations(only single-sheet schematics, PCB size limits and only 2 layers, no commercial use) and it is available for Linux, Windows and Mac. Many PCB manufacturers(especially those focused on hobbyists) offer direct eagle support, so you don't have to fiddle around with CAM-Files, which can be a pain in the ass. However, the feature set is somewhat outdated and the controls are kind of counterintuitive.
(2) DesignSpark PCB - My personal favourite. Completely free without restrictions, even for commercial use. The feature set and interface are neat and modern and much easier to learn than Eagle. It's got interfaces for LTSpice and other simulators, it has some very useful calculators built in(trace resistance, current limits etc) and it's got a 3D-View which for me is a dealbreaker with many other tools because it is just awesome to be able to fully visualize your design before production(especially when you're trying to design a case around it and stuff like that). However, it is strongly tied into RS Components and will try to sell you RS Components products(i.e. you get their libraries and so on). Not a big deal for me, but maybe for others.
(3) DipTrace - Just check out Dave's reviews of DipTrace:
http://www.eevblog.com/2012/03/09/eevblog-255-diptrace-pcb-cad-first-impressions/.
There's also KiCAD(fully open source, nice!), Target 3001 and a ton of other PCB design/schematic capture software and most have a free license that fits every beginners needs!
All in all - save the 100 bucks and buy a reasonable DMM with that.
Also do not buy an expensive bench supply, its no use for fiddling around with arduinos, you will never need that kind of precision or three channels or whatever. If arduino really is all you need go buy a 5V 1A plugpack and build an adapter for your breadboards and you're all set, if you do some other stuff and need a variable supply, just spend 100 bucks on a reasonable single channel 30V 3A supply. Also, consider building it yourself - there's tons of tutorials for stuff like that all over the internet. A DS832 is just waaaay over the top for a beginner.