Hello there,
I always see people get super paranoid about these kinds of measurements yet they are done every day without incident.
Years ago I used the method of cutting the ground pin off of the scopes line cord plug for literally 100's of measurements. Many people I knew did the same thing, over and over and over and over and over again. None of them died. None of them even got shocked. These were all CRT type scopes.
The key point here is you just have to pay attention to what you are doing when making ANY measurement of line voltages, 120vac or 230vac, or even 440vac. It's not limited to scopes. When you use a regular voltmeter, you have to pay attention to where your hands and feet are, as to what they are touching at all times. It's either that, or pay someone to do the measurements for you.
These days battery powered scopes are somewhat cheap you can get one now for less than $30 that will do line frequency measurements with ease. That would be the recommended method for today, but you still have to pay attention to what your hands and feet are touching when you do the measurements.
1. Don't touch any metal connected to any wire.
2. Don't stand on concrete or any electrically conductive floor, don't stand in water.
Do some reading on the web for how to make line voltage measurements and precautions, you should be ok.