How will introducing another unknown element help with adjustment? What's your reference signal, do you know what the output signal should look like? Do they specify aberrations with your layout and load? What problem are you trying to solve?
All good points. I don't have access to any other scope or equipment to check the finished circuit against. The only "reference" would be Fig.2 in that link, and of course, is merely what they achieved with their circuit. However, it seems to me that I could use a short co-ax cable with bnc connectors to connect this circuit directly to the scope, take a screen shot, and use that as a reference to ensure the probe performance is adjusted to be no worse than a direct cable, no?
As for the problem I'm trying to solve: perhaps none whatsoever. I really don't know enough about all this, which is why my original question was "how important or useful would it be to adjust these to the Rigol scope (post-100MHz hack)?" The Rigol scope inputs are 15pF, the cables came from the factory adjusted to 20pF. Does that mismatch matter? Of course, the Previous Owner may have adjusted them to his particular equipment already, so I really have no way of knowing what they are currently set to anyway.
If the truth be told, this is as much of a learning exercise as anything. I will probably never have a need for a 100MHz scope. (see, I got the right 'M' this time -- I'm learning already

). My last scope was an old Tek 20 MHz unit that was hopelessly inaccurate and out of calibration with one working pre-amp. Most of what I do is automotive and motor control. I could probably get away with one of those hand-held or USB scopes. However, for the price, I figured I may as well upgrade to the Rigol and if I've got it, I may as well ensure it is operating at it's best.
Who knows where this learning process may take me? Electronics have always intrigued me. I used to play around making various beginner-type circuits, but then I had to raise a family and access to components dropped off sharply around here anyway when Radio Shack went out of business (I'm in a very rural part of Canada). Flash forward 30 years, I have some free time on my hands and this past summer a shop opened only a few hours away stocked with all sorts of goodies...