Okay, I thought you mean the primary.
For the secondary, it's of course current times voltage again, as usual. And this time you need the plots showing how secondary side voltage drop (Vce) varies depending on secondary side collector current (Ic) and primary side LED current (If). My PC817 daatsheet from Sharp has two plots, one showing Vce vs If for a few different values of Ic and another showing Vce vs Ic for a few chosen If.
The specifications table also shows "collector to emitter saturation voltage", which is guaranteed never to be exceeded as long as If is high enough and Ic is low enough. It is specified as 0.2V maximum for If=20mA and Ic=1mA in my datasheet.