Hello,
With many op amps that run off of a single supply, their outputs can not go all the way to 0.000 volts, instead they only get down to maybe 0.025 volts to 0.200 volts. With that added diode, it drops around 0.600 volts, so the output can get all the way to 0.000 volts even with a single supply.
That's one possibility although one diode is usually enough for that and the pulldown resistor is usually smaller than that 1 Megohm that we see here.
It can also just be there to prevent a negative output.