AAgh!! I made a typo searching google and didn't notice then copy/pasted the bad part number and result.
Please *IGNORE* my stupidity.
Siwastaja has nailed it. I'm surprised its even outputting 3V as I would expect overvoltage to blow the LMR62014's output transistor, dead short to ground. Ground /SHDN and see if the SW pin is lower than Vin or if the transformer is getting hot.
The LMR62014 may still be viable if you can find a higher ratio pulse transformer. Maybe one with a center tap on the low turns count side?
Another option, keeping the ATB3225 would be to use a voltage doubling rectifier so the LMR62014 only 'sees' 5V+90V/10 (=14V) reflected peak at SW, but you still get 180V out.