At my school I saw once a panel with Italy map drawing on one side, and many wires on the back. There were a lamp and many plugs on each region and its name, all names written together below the map. You had a wire ended with banana male plugs. If you inserted the two plugs one on the name and one on the matching region, the lamp lit up, supplied by a battery.
The same teacher that built that panel also teached us a little programming with Logo (we were only 6-11 years old!).
Other things I played with were telephone microphones, phones and batteries, with which you can actually build a phone (with such an equipment once we cheated at an oral test at school, the people suggested aswers from the last desk!
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It is also interesting to see that a chain formed by many people hand in hand can be a sufficiently conductive path to light up an LED from a 5V source (the switch can be an arm).
I often had thought about making this kind of things for kids, since I'm a scout chief, but only your question has now unlocked my memory...