Combine R1 and R3 into a single resistor, located in the existing position for R1.
Assume a constant forward voltage Vf[led] for the LED, and a different constant voltage Vf[d] for the diode.
Call the battery -ve terminal GND. Now you know the voltages (with respect to GND) on both sides of both diodes.
I2 = (Vf[led] - Vf[d]) / R2
I1 = (Vs - Vf[led]) / (R1 + R3)
I3 = I1 - I2
... and solve from there.