Over what kind of time scale, I guess? Silver tins very well, but will tarnish eventually and then it's harder to tin (if the silver plate corrodes through, it'll also be very slightly higher resistance, but not enough to notice). Tin plate always tins well, though as it gets older and tarnished, it takes a little more flux to work through.
If you're going to end up tacking stuff onto it, conductivity probably doesn't matter; the silver will be dissolved by the solder anyway. Might still have some use as coil winding, if you ever to some RF stuff, but not a big deal.
Tim