Whenever possible live probing should be avoided, make connections to a disconnected (unplug and have cord end visible as a confirmation!) DUT, then power up and observe hands free. I think this gives more time to evaluate the setup and catch any nasty mistakes. If you must poke around, use shrouded probes, DO NOT FORGET about the ground ring on a scope probe.
I second having the DUT on a 5mA RCD/GFCI at the bench, makes those oopsies to earth a lot less spectacular/destructive/deadly.
That said, I think rule #1 is to understand what you're doing, i.e. what you're working on and the tools you're using, do not proceed without solid understanding. All the other stuff just helps prevent death when mistakes are inevitably made.