The Philips has a very unusual and "non-traditional" layout, not that it ultimately matters, but just say'n.
There is little practical difference between 50MHz and 60MHz bandwidth.
The Philips has extra on-screen measurement capability if that matters to you,
Usually the idea of getting a used analog scope is so you have an analog scope on hand, and you can learn stuff, and to get one cheaply.
The analog scope will most likely be superseded for most everyday use when you get the Rigol, usually because the form factor is much nicer, and it has proper DSO capability.
So I'd say that it's not worth paying the extra for the 100MHz bandwidth, unless you have a specific need.
I'd probably have the 2225, just because it's a basic no nonsense analog scope. But I have personally lusted after that Philips with the LCD displays since I was a kid :->
Dave.