Those radiosonde batteries are a special design, an 18V battery using a stack of dry electrodes, zinc sheet anode, manganese dioxide and ammonium perchlorate with sawdust powder blend electrolyte and a graphite cathode on a zinc sheet, which is also the anode of the next cell in the series pack. These are in a waxed paper housing with a small vent on top, and a hole at the base that allows you to activate them. Activation is simple, you take it out of the sealed plastic pouch it comes in, in the base of the sonde, and dunk it in water for 5 minutes to wet the electodes, which then wet the electrolyte and activate the battery.
Then you put it back in, plug in the power lead and close the case, and take the small strip of teletype tape ( or for some the calibration data printed on a strip of paper, for the particular device from the manufacturer, but the tape is machine readable) and put it in the recorder to get the calibration data for the particular unit, as they can have a large unit to unit variation, and there is no cal before flight. Then you attach the yellow handle to the inflated balloon, which also seals the rubber fill section, unwind the cord and let it go.