Well basically in order to change from I believe what is called a one-pipe system to a two-pipe system (plumbers suck at naming things btw), it would be akin to a complete 'rewire'. Not only would this involve, well, moving out as all the floors upstairs and downstairs would need to come up, but it would involve tracking large recesses up through the block walls, replastering those after the pipes and installed and fitting these distribution valves, powering them, running control cables and buying hundreds of feet of plastic piping. Not something I would be prepared to do myself. Not least as there are standards and building regulations to adhere to. The reason you care about building stanards and regulations is because if you want to sell your house it's important, but more importantly for your building and contents insurance, it's important.
So I am swapping the heating system from oil fired to gas fired and replumbing the storage tank system to an on demand system. This will reuse the existing copper piping. The cost is around £2700. A complete re-plumb with all plastic piping and two-pipe parallel radiators would, most likely, cost me 2 or 3 times that for a professional installer to do it and I would, most likely need to spend a week in a hotel, costing another £1000. Of course if I was going to do that, I would get the 1970s electrics rewired at the same time, to do otherwise would be silly. So add another 2 or 3 grand. Suddenly it becomes a complete renovation and while that may increase the valve of my house by 10 or 15 thousand, it will cost me something similar and take a few weeks where I would probably need to move out.
As to running mains to the radiators. First I don't need/want to control them all and second the mains is already distributed around the house with plug sockets existing close to the radiators in question anyway, so all I really need to do is run a few feet of white, flat, two core along (or behind) the skirting board to the radiators. Hide the remote relays below the radiators and job is done.