Hmm, let's look at things then.
- Gain is already high. This helps some because the error from ideal (i.e., 201 according to the resistors -- assuming their values are exact) will be larger.
- But, you're still trying to subtract a small difference out of a big measurement (i.e., the couple milivolts the op-amp needs at its input to do its job, out of a measurement of 10V). Anywhere you see a scaling issue like this -- physically or numerically -- proceed cautiously.
- Check your expectations. You should intuitively expect gain is slightly less than 201, because the gain is finite. How does this compare to your measurement of 204?
- Aol = -13668 sounds pretty reasonable to me. It's wrong, but that's a byproduct of the measurement, which is never exactly correct either (even doing this in SPICE, you are limited by finite tolerance parameters).
- Lastly, consider sources of error in both the input and output voltages. How did you measure them? If on a scope, you're assuming the scales are *exactly* in the proportion given (i.e., 10mV/div is exactly 200 times more sensitive than 2V/div or whatever). What is the effect if they are not? And how much are they allowed to be off by? (For a scope, usually a few percent -- an error on the order of 1/200th is impossible to be sure of!)
If you have access to a very good ratio (such as a ratio transformer), you could possibly do the measurement on the same scale, so that both measurements have the same proportional error. You could also do it differentially (let the circuit do the actual subtraction for you!), or use existing components (measure the feedback directly?).
Overall this sounds more like a lesson in tolerances and errors -- and statistics -- than electronics. Hopefully you'll have some courses soon to round that out?
Tim