I don't know if this is widely known or not, but when desoldering components many add additional solder to help with the desoldering process, i.e. for a better heat transfer and to break any oxide layers. From my experience it is the flux core in the solder what helps, not so much the solder. So you can simply add flux to the solder joints before desoldering the component and won't wasting solder. A simple flux made from colophony and IPA works fine. Works also great with a desoldering gun/station. For really crusty joints you still might have to add a little bit solder.