How long can you let the car sit without needing to charge the caps again?
The biggest drawback with supercaps is their high leakage relative to conventional batteries.
Actually, leakage is not an issue at all. People seem to expect supercaps to run flat quickly with zero load but that's not what i've found at all.
I ran a test to check this before starting the project. I charged up all caps to full voltage (2.5V) and left them for a few weeks.
Extrapolating the results the leakage was such that they wont have any problem staying above 80% charge for at least 2 months.
Keep in mind though, that the leakage reduces as they discharge so the leakage will never run them dead flat.
I charged up all 9 caps for the leakage test but only put 6 in the car. The other 3 have been sitting around since then.
So I just went now and checked them. They're at 2.13V 2.08V 2.01V
So they lost ~0.4V in about 6 months since they were charged.
Assuming in the car a full charge of 14.2V from the alternator, after 6 months with no load you'd expect about 11.8V
What IS an issue however, is the current draw from the car alarm, ECU memory refresh and cd/radio memory.
Because of those loads the car only lasts about 4-5 days of sitting around before the caps will fall below whats needed to start the engine.
I've not got around to actually measuring or fixing this issue because i already have a 14V DC charger in the garage which i setup a few years back so my carPC can run continuously while I program and test apps for it from inside the house.
I mounted a charge socket and LAN socket on the car so I've been keeping that charging socket plugged in so it hasn't been an issue.
I either have to reduce the cars standby current draw or install a cutoff relay to auto disconnect the dash power feed when the capacitor array falls below say 10V.