Injectors are optimised to spray correctly at a certain fuel pressure range.
Altering the pintle position when open will affect the pressure of the fuel exiting the valve portion of the injector before it hits the director plate that actually determines spray pattern and droplet size. Less open pintle = less flow = less pressure at the plate and sub-optimal spray pattern.
Also, the injectors in a manifold injection system don't actually spray directly into the open combustion chamber anyway, they spray onto the back of the intake valves to help keep them cool and to evaporate the fuel for better atomization.
My thinking to increase atomization would be to increase fuel pressure then decrease the injector on-time to compensate for correct air/fuel ratios.
But before diving into injector droplet size, I'd be doing more 'tried and true' methods of increasing efficiency and power, like forced induction, porting and polishing the intake system, flow matching the intake and exhaust ports, adjusting intake and exhaust runner lengths to optimise the powerband for the application at hand and designing the exhaust system to scavenge at the same RPM range.
Then use an aftermarket ECU to tune the car to a better/leaner tune on a dyno instead of relying on an overly conservative OEM tune.