The real triode structure produces a warm, unique vacuum tube sound, delivering excellent linearity.
What is so unique about vacuum tube sound that can't be reproduced by a digital post-processing?
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Sonically, you can get very similiar results, but sometimes the dynamics and "feel" of playing through digitally emulated vacuum tubes is just off. This is especially important in certain styles of music, and with certain guitar tones (Blues music comes to mind)! Of course, I am specially referring to vacuum tube guitar amps, many of which have little to no negative feedback.
Of course, this is a subjective opinion, but one that I have found many musicians I know have. I wonder if it has to do with the digital approximation of the transfer curves not being completely accurate? Also might be manufacturing tolerance of tubes, from my understanding, the parameter variation is pretty wide.