It depends on what you mean by respect?
It depends on the voltage, 50VAC will whack you much harder than 50VDC will but a huge chunky 48V battery pack will hit you much harder when short circuited with a spanner than the mains.
Of course I'd treat 240VDC with equal or greater caution than 240VAC 50Hz, even though I know the shock may not be so severe, such an installation won't have an RCD (GFCI in US), the short circuit current will be higher, the arc flash will be more severe and there won't be a breaker at the battery terminals.
Different forms of electrical energy have different hazards, it's important to be aware of them and exercise caution when dealing with them.
I suppose another thing that makes working with live batteries safer (at any voltage) than mains, in some respects, is you can easily isolate them from ground and other circuits, making a shock impossible unless you touch two terminals at a high enough potential difference. For example if you take a 600V installation composed of 50 12V SLAs connected in series, the shock hazard may be greater than 230VAC but if you remove the earth connection and open the main isolator, disconnecting it from the appliance, the only way to receive a nasty shock is to touch two terminals with more than five batteries in series so you should be fine assembling/disassembling the pack, providing you know what you're doing. Thiing about this makes me feel better about working with DC systems now.