We have the green energy offers in the Netherlands as well here, and you basically get the same electricity and same price. So it doesn't do anything at all, just says it's green (marketing)
If you do pay more, I still think you get the same electricity but your money is used to invest in new plants and good initiatives. A wind mill produces more electricity when it's windy, a solar panel when it's sunny. They can be predicted short term, but some people claim you always need a gas power station or something to back it up in case.
And yep, you need to keep it running, because such a station costs days to boot up.
I do believe in Electric cars. If you look at it, some people talk about hydrogen being great, because it can be produced with green energy. Well, so you can power electric cars. Hydrogen fuel cells are just inremote, I believe not even proven reliably in a lab and require all kinds of strange materials.
Batteries are getting better and better. I recently read some wikipedia article about lithium air batteries, which are very light (as the name suggests).
A fossil fueled car is so inefficient. Think about it: let's pump up oil, 'filter' it to diesel (costs a ton of energy), ship it to a gas station (a truck has to ship it), use many pumps to move the stuff around (although this is a small fraction of energy, you still need the things!) and then use a horribly inefficient engine with technology from 1893 to burn it. A maximum efficiency figure for a diesel is 40-50% maximum. For a petrol this figure is about half. A big (gas) power station has the same efficiency and requires less trouble getting energy transported to your car.
The efficiency of the car, electrical grid and charging/discharging may be a few % as well. But the idea is that you shouldn't use a gas power station to power your electric car, but green energy. If that is accomplished, your car is basically running CO2 free (except the effort required to make it - but I don't know how much bogus is made up in those figures).
In the end, you CAN make an electric car CO2 free, and you can never do that to a diesel or petrol car. Those two will always ignite fuel in a 1890's technology engine.
We just need better battery technology (lighter, more dense, less expensive) and a smart power grid. Smart Grids were cars can request a charge period, and the grid figures out what the most efficient way is of charging all the cars on the grid (assuming you have like 50% of the population on electric).