AC voltage accuracy will depend on the frequency. You can find some frequency response plots for oscilloscopes, this should give you an idea of the error. For most low-end scopes, the error at the rated bandwidth should be about 30%. So for a 100 MHz scope, the amplitude of a 100 MHz sine will be 30% low. Best case (possibly low frequencies) may be equal to the DC spec, worst case will be 30% off. That's why there's no single AC voltage spec in the manual.
Any quantization error will be in addition to the error induced by frequency response.