I'd have thought all commercial device programmers would still have config info for old CPUs like this. My Topmax programmer does, and that's from around 2001. See pic.
Can't recall if I ever programmed an 8749, but I did do a lot of work with Dallas DS5000's, which are 8051 compatible. I think we used a PL1 compiler.
It's tempting to think of using the old CPUs in designs if you have tubes full of them, isn't it? But then you wake up and think, no, that would be nuts. Completely unmanufacturable, pointless, and there are vastly more capable current CPU systems, like Arduino ATMega168 for $1.20 each.
Still would be sad to bin them though. I'm all in favor of keeping all such old component stock. If only for future maintenance of systems for historical interest.