I would ignore the transmitter in the first instance and pay attention to the receiver and its aerials (There are much bigger wins to be had here).
Using good quality Yagis cut for the correct band (Not broadband ones) with a diversity receiver and GOOD quality coax is a major win as much for the reduction in potential interference from behind the aerials as for the increased signal strength. You can gain much more here then the 6dB that is the difference between 25mW and 100mW, and it does not hurt your battery life.
Note however that preamps (unless carefully selected to make up cable and distribution losses) are usually not a win, they tend to increase the sensitivity to overload as much as they improve the RF noise figure.
The power limits usually have more to do with limiting the interference potential then any health concerns (After all a cell phone can put out a watt or so).
The OEM will have set up the transmitters to suit your licensing regime. In the UK it is 10mW for a handheld and 25mW for a body worn pack unless you make special arrangements, not usually a problem.
I have licensed 5W portable link transmitters before now, but that is kind of specialist.