Quality electroplating is much more than just having metal ions collect onto a surface. Getting excellent adhesion of the plated metal to the substrate is not trivial or easy. Add the difficult environment of a soldering iron tip with materials with different thermal coeficients of expansion and repeated aggressive thermal cycling that incur heavy shear stresses at the plating/base metal interface. Good luck with DIY on this.
Back on topic, I know this will start a major firestorm but here goes. For the last aprox 35 years I have always had a tin of Nocorrode brand zinc chloride paste flux right next to my soldering irons. If my tip is not bright I do a quick dip in the flux and then wipe on the wet sponge. Instant perfectly tinned tip all the time. I probably do 10 or 15 joints between dips. I NEVER put that flux directly on the parts I am soldering, only to clean the tip and then a sponge wipe. I use traditonal rosin based electronic fluxes for any directly applied fluxing. I have not noticed any substantial decrease in tip life and my tips always look like new. I still have things around soldered with this method that are 35+ years old (a Heathkit decade box) no evidence of abnormal corrosion. I don't think any functional amount of zinc chloride gets to the solder joint. I completely understand that if you dipped a stranded wire in the zinc chloride flux and then solder it in a joint you are asking for major trouble. The flux will wick up the strands and start destroying things in short order. DONT USE ZINC CHLORIDE FLUX FOR ELECTRONIC FLUXING. I realize that for meeting many specs this procedure would be competely forbidden.
Let the torrent of abusive comments begin.