Congratulations on your new job! I hope you get a lot of technical satisfaction out of it.
Doing embedded and hardware prototyping at a desk?
(1) Suggest you invest is a burn proof antistatic mat. If it is conductive, tie it to earth. Add an antistatic wrist strap connection.
(2) Pull the desk away from the wall so you can pass up IEC mains plugs and other cables. Keep the rats nest of cables away from your desktop. (Or is that "desk top" with a space?)
(3) Invest in some headphones so you can block out office chatter and play chill or classical music whilst programming. Even so, it does not work if you have an office idiot stationed nearby. I once had one who had a bad habit of whistling random notes like a bird for hours on end.
(4) If your desk is near a coffee vending machine, move to another desk unless you are hearing impaired.
(5) Make sure you buy plenty of power boards. You will need them.
(6) Good lighting is vital. Get some decent overhead fluorescent lights and invest in an decent illuminated magnifier. I once bought an LED one from Element 14 with the big concertina arms that clamped to the desk edge. It was fabulous.
(7) You might be able to drape your probes and leads over the partition. If not, invest in a cable rack. Label your own CRO probes. When people borrow them, they tend to lose the coloured rings or probe tips, or lose the whole probe.
(8 ) Use a drawer for miscellaneous bits, and other drawers for paperwork. Every Friday night, clean up you desk before you go home. That way Monday morning you start afresh, feeling good you have a clean, neat electronics desk. It is worth the investment of 5 minutes to do this. That includes wiping the desk top (or is that "desktop" without the space?) down with a cloth with some mild detergent.
(9) Keep the PC off the desk. It wastes space. If it is on the carpet, you might need to open it and clean it out every 12 months due to excessive dust.
(10) Remember you spend 8 or more hours a day there, so make the electronics desk your home away from home. Nothing beats a well laid out electronics desk. It makes life enjoyable. But there is nothing worse than a big mess and you cannot find your probe tip because it is hidden under a sea of cables. Working in a pigsty does not tend to send a message of professionalism either.
Hope these hints are helpful. Once again, contratulations.