Unless you are buying large quantities of PCBs it is unlikely that you can specify the layer stackup freely. Go to your preferred supplier JLPCB, WE Direkt, etc. and look what their standard stackup for a 4-layer board is.
In any case, just having ground/vcc on inner layers will be good enough. The only reason to care about the specific layer separation is if you are trying to do controlled impedance traces for RF or very high speed digital interfaces.