I've used a dremel with PCBs before, and it's really not a great way of doing things. I just used one of the emery cutoff wheels.
If you really want a straight, nicely cut edge, either:
a) Score and snap, then use a file.
b) Hacksaw along it (ie. long, but shallow cut), then use a file.
c) Go to the trouble of making some sort of mini-table saw arrangement (using a dremel or otherwise) with a rip fence.
A rotary tool doesn't lend itself well to a straight edge unless it's configured as a table saw, table router or milling machine.
I bought a mini table saw years ago and it works wonders for PCBs, but I can't stress enough how much better the lowly hacksaw is than a handheld dremel.