First of all you should make sure that you
really need matched time/delay. Often times a little skew is totally fine.
But as a rough rule of thumb signal speed on inner layers is about 1,5x10^8 m/s² and signal speed on outer layers is about 1,7x10^8 m/s² (assuming some sort of FR4 board). So one thing you can do is to simply make the inner conductors ~10-15% percent shorter than the outer conductors.
If you need a little more accuracy:
Since propagation speed depends on the relative dielectric constant (and the relative permeability) of the materials around the conductor (usually air, solder mask or some sort of FR4 material), you need those values from your PCB supplier (or the data sheet of the material they are using). The relative dielectric constant for FR4 is usually around 3.8 to 4.5. The tricky part are the outer conductors, because their surrounding material is not uniform. That's where the "effective dielectric constant" comes into play. I think the Saturn PCB Toolkit hat some tools to estimate signal speed on inner and outer layers based on approximation formulas.
For even more accuracy a decent PCB supplier can tell you the propagation speed of each layer. Usually they throw their process knowledge (tolerances, ...) and material properties into a field solver and come up with more accurate values.
But my suspicion is that you don't need this kind of accuracy for matching your trace delay times