It’s been a while since I used the DE0 but before programming the pins are all pulled to 1 by a weak pull-up,and there is no ready way to change that, this is also the default for intel and lattice as said before with Xilinx there is a pin, depending upon its voltage the others are pulled up or down at boot, however this is by far the exception and not the rule, also usually the dev boards don’t make it easy to change setting (no jumpers or solder bridges, usually just a non descript 0402 resistor somewhere)
This is a big trap for first time users, that are used to IC’s with sane defaults (everything off or tristate unless I say so)
The reason this is done is for power consumption, using all pins to ground default will increase it considerably (somewhere in the range of 2x to 5x IIRC) I don’t know why for sure but my theory is that there is more internal leakage current when the pin is at 0 than otherwise