No worry, plain masking tape is plenty black at thermal wavelengths. Even better, vinyl electrical tape!
Other tapes tend to do poorly: yellow transformer tape (polyester/acrylic?), or clear gold (polyimide), are typically too thin (fractional wavelength) so don't increase emissivity as much as you'd expect from their materials (which is the emissivity of bulk material).
Same goes for ink -- even a heavy mark (let dry and re-draw multiple times) from a permanent marker, while enough to be visible in thermal IR, still has quite low emissivity. A nice thick layer from a paint, grease or wax pen(cil) does nicely, however.
You can also look for bright peaks -- occasionally you'll find an inside corner with total internal reflection, which therefore acts as an accidental black-body resonator, thus representing the actual temperature of the metal. These are quite hard to spot / rare to find with low resolution consumer cameras, though. (As I recall from a good industrial cam, philips screws and inside corners of heatsinks can occasionally do this. But the spot size is quite small -- specular reflections basically. To be more specific: the heatsink temperature is at least max(<pixels within the region of the heatsink>) -- but can still be more than that, because you still don't really know the emissivity of those brightest spots.)
Tim