There are mPCIe cards
with a SATA chipset on the board, like Advantech EMIO-200SA sold by Mouser (923-EMIO-200SA-MP01E, 25€, but unfortunately not in stock) and Digikey (also not in stock), which has *two* SATA III ports. To repeat, it is not an mSATA M.2 card, it is an mPCIe card with a SATA chipset on it, from 2015 or so.
(As of 2023-02-01, the only place that I can find that claims to have them in stock is
micro-semiconductor.com in Hong Kong. However, if I wanted one, I would definitely look at
Advantech Online (EU), and enquire about it, because the page shows "Available for Delivery".)