Just a few questions that come to my mind while contemplating on the topic
1. Why is the silicon wafer when its being manufactured from a liquid kind of state not 100% pure silicon?. Why is it doped to become an N type or a P Type substrate? I mean some dopants are added to the mix when the wafer is being manufactured?
This is a deep and involved topic with lots of history.
Lets work backwords from the transistor structure.
An N-channel transistor needs N+ source and drain (the "+" indicates heavy doping of donor atoms) diffused into silicon doped with acceptor atoms so that the underlying material is doped P type. In order to achieve desired transistor performance, that material is very lightly doped...we call it P- where the "minus" means lightly doped. In the above, Phosphorous is typically used as a donor dopant, and Boron is used as an acceptor dopant.
If all you wanted to build were N-channel transistors, you could manufacture a silicon wafer that has a P- doping. In fact, early MOS technology was either totally N-channel, or totally P-channel. Of course, for a totally P-channel circuit, the wafer would have to be manufactured with N- doping.
Wafers come from silicon ingots, or boules, that are manufactured using the Czochralski method. Molten silicon is gradually extracted starting with a crystalline seed. For doping requirements, the molten silicon can be doped with donors or acceptors to achieve the desired doping.
Nobody uses NMOS, or PMOS any more. CMOS instead!! So, how do you put a p-channel transistor in a wafer that is already doped P- ??
Well, you have to create regions on the wafer that are lightly doped N-. These regions are called "wells." So, for CMOS, you may start with a lightly doped P- wafer as the basic substrate, then create well that is doped N- (either by ion implantation, or diffusion, or combination of both). Withing the n-well, you can put p-channel transistors. In the regions outside of the well, you can put the n-channel transtors. Now you have CMOS!!
That is pretty much it, except for about a million other details.
2. Why is an epitaxial coating done over the silicon wafer before any other processes are done?
Epi layers can be created with more precise and tuned properties than can be achieved with the C-growth method. The underlying substrate can be high conductivity enabling better performance under certain condition.
3. Is there a comprehensive list of steps for silicon chip fabrication?
Yes. Have you googled for this?
Also, the processing steps of changed over the years-- metal-gate, silicon-gate, oxide-isolated, shallow-tranch isolation, on and on...
Go here:
https://aicdesign.org/wp-content/uploads/2018/08/lecture02-131209.pdf