Usually architectures are ranked by the apparent size of their ALU. ("apparent", because it seems like the Z80 had a 4bit ALU, and just always did at least two operations...)
I'd rate the 8bit PICs (PIC16f...) as true 8bit architectures. 8bit ALU, 8bit register(s), less than 8bit address space for data (until you add the banking.) The PC and instruction word are wider, but "Harvard architecture", so those are pretty separate from everything else. (and the baseline PICs with essentually 9bit PCs (plus another bank) and only 8 bits of address in a "call" instruction!)
5V designs
not been mentioned yet: Toshiba has some pretty substantial CM3 ARM chips that will run on 5V.
The NXP ones are the "Kinetis E" series.So they're not uncommon. I think the surprising bit is that none of the "hobbyist" vendors (Arduino, Adafruit, Sparkfun, PJRC, etc) seems to have jumped on any of the 5V 32bit cpus...