Hi,
I recently designed a DC/DC converter operating in a similar voltage range, using only passive cooling. The maximum output current of the design I did was 20A, but this was limited only by the customer's specification.
I am quite busy at the moment, so I can't get involved directly, but I recommend looking at the LT8210 from Analog Devices. This is a buck/boost converter, but in the design I did it spends most of its time in boost mode. At switching frequencies of 100kHz the MOSFETs barely got hotter than about 40 degC when handling 400W. The design was based on sandwiching the board to an aluminium heatsink using a thermal filler pad from Wurth electronics (401 010 05).
The LT8210 also features an output to control a polarity protection MOSFET, which you may find useful in your application.
Best wishes,
Greg