That looks like oxidized copper to me.
The trimming axles might be made of brass (which would contain copper), judging from the yellow-ish color of the other pots.
I can't imagine, why only the middle PCB is affected.
Also take notice, that the leftmost trim pot in the middle, marked "BW" is as well discolored / darkened, compared to the lower one.
Are these trim pots from BOURNS?
Frank