JLC PCB has an FAQ entry about stackups with
pictures indicating a 0.18 mm prepreg between top and inner1 (for a 4-layer).
However, they also have
.stackup files suitable for Altium that, for 4-layer boards, show two different stackups. The same two stackups are shown
here. Here, depending on the fiberglass weave, one gets either 0.1 mm or 0.2 mm between outer and inner layers.
I took some measurements from
Dave's section of the board (loaded the image into an editor, counted pixels between layers and scaled by the 1.6mm board thickness); it seems to show something more like 0.22mm. Given the image resolution, the error is ~0.05mm assuming no parallax.

Does anyone know which one is actually used for 4-layer prototypes? I'm hoping to make a microstrip or CPW to route some traces at ~600 MHz.