Yes for PTFE , I have read that 75 Ohms have PTFE and most of the 50 Ohms have nylon ( PA66 ) but that possible to locate BNC 50 Ohms with PTFE , I will check in my available batches
I don’t think one can make such a generalization. 50 ohm BNCs use a wide variety of dielectrics: polypropylene (PP), PBT, nylon (PA), Delrin (POM), polymethylpentene (PMP, TPX) and PTFE were just what I found by looking at a couple of standard, low-cost (under $5) BNC connectors on DigiKey.
And conversely, it’s easy to find 75 ohm BNCs with dielectrics that aren’t PTFE.
The only concern I have seen on BNC is the maximum possible matting before contact surface damage as from main brand as Amphenol they rate at 500 connections before possible contact damage ( galling / fretting)
I would expect contact deformation to be a bigger issue than galling or fretting.
But regardless, I mean… BNCs are used on test equipment here and there. Like, say, every oscilloscope, function generator, and bench LCR. And tons of broadcast video equipment. Surely if BNCs lacked sufficient robustness, they would not be used on such a huge variety of equipment that is plugged and unplugged constantly.
If you use decent quality connectors, connector life should not even remotely be a problem.