A transistor can be used as a zener (usually around 6-8 V), but this is usually a rather noisy zener. It is common to use this if one want's a zener as a noise generator.
With those compensated zeners the linear TC depends on the current and could thus be adjusted, but there is an square law contribution that is usually rather similar among samples. So this would not get better with references in series. The linear TC at a nominal current might get a little better by chance. If the individual zero TC currents are not to different, one could get away with a single current adjusting the overall linear TC.
Long time drift also tends to be similar between units. So there is not much improvement expected.