So you want to force current with the K 220, measure its value with the 3458A and then the voltage accross the resistor? Or how do you determine the exact current (the K 220 allone will be way too unprecise)? You would need two 3458A meters at a time, on for current measurement and one for voltage (as you cannot assume that the K 220 current output is fully independent of the load when you changeover from current to voltage measurement with one meter).
But what sense would that make? The current uncertainty of the 3458A is worse than the ohms uncertainty (simple spec comparison, pretty obvious). Plus you add the drift (temp, noise...) of the K 220. I am not getting the rational of why you even consider this, maybe you can explain.