Are a couple of ppm of better linearity really worth it?
Because of the Footnote you are in trouble as soon as you leave the 10%
Let's say you want to transfer a LTZ1000 7.15V to a 10V standard
With the 3458A it would be:
sqrt( (0.05ppm + 10/7.15 * 0.05)² + (0.05ppm + 10/10 * 0.05ppm)² ) = sqrt( 0.12² + 0.1² ) = 0.16 ppm
If you apply the 24h specs of the 8588A:
sqrt( (0.5ppm + 10/7.15 * 0.05)² + (0.5ppm + 10/10 * 0.05ppm)² ) = sqrt( 0.57² + 0.55² ) = 0.8 ppm
But that is just a part of the uncertainty. You have to add the noise of the readings and the uncertainty of your 10V source.
As long as you compare two 10V standards the specs for both meters is the same (but the question is then, if it makes sense to compare 10V against 10V in the 10V range).
We are not talking about a couple of ppm, but 0.6ppm on paper. Everything seems like the 8588A is in the same region of linearity and this could be verified for your very instrument. But as long it is not, you better stick to the specs on paper.
If the DMM is also your 10V reference, than the 2.7ppm vs. 4ppm on 10V might be also an argument for the 1year spec.