I looked at the instructable link you gave.
First, that design does not somehow intercept data from the DMM, but instead, it uses the PIC ADC to read the 0 to 200 mV input voltage that the DMM is going to also digitize to get its display. The PIC then sends the result of its own ADC to the computer over RS-232. This is not what you want.
Second, that design is inherently
extremely unsafe, as there is no isolation between the meter and the computer. The computer's ground will be connected to (I assume) the meter's common lead. So the meter is no longer floating, but is ground referenced. Don't. Just don't.
All "real" external data interfaces use optical isolation. Sometimes optocouplers are used internally, other times, the actual connection to the meter is using a "cable" that actually has IR Tx/Rx, but no electrical connections.
Im a bit confused though because the data data sheet says the chip has EEPROM and SRAM bit then under special chip features it says the chip is OTP rom, one time programmable.
The datasheet says it has EPROM (note the single E for Electronically Programmable ROM, as opposed to the double EE having Erasable in it.) That makes it OTP.
EPROM = Erasable Programmable ROM. If the microcontroller die is in an expensive "windowed" package, then it can be erased by exposure to UV light. The exact same die in a black epoxy package is effectively OTP, since it can't be exposed to UV to be erased. This used to be very common; you would use one or more of the expensive erasable versions for development, and use the OTP one (which is always the exact same die) for the final product. These days, FLASH program memory is almost universal.
EEPROM =
Electrically Erasable Programmable ROM.