Then don't worry, datasheet only show which pins which you can use with ADC but without your interaction will not take any pin by itself, to connect pins which you want first you must connect it to ADC
This is taken from STM32 library example:
/**
* @brief Configures the different GPIO ports.
* @param None
* @retval None
*/
void GPIO_Configuration(void)
{
GPIO_InitTypeDef GPIO_InitStructure;
/* Configure PC.02, PC.03 and PC.04 (ADC Channel12, ADC Channel13 and
ADC Channel14) as analog inputs */
GPIO_InitStructure.GPIO_Pin = GPIO_Pin_2 | GPIO_Pin_3 | GPIO_Pin_4;
GPIO_InitStructure.GPIO_Mode = GPIO_Mode_AIN;
GPIO_Init(GPIOC, &GPIO_InitStructure);
}
So here only 3 channels of ADC are configuret as Alternate Input, by default all IO ports (except JTAG ports) are configured as general GPIO pins which are not connected to any special peripherials, just datasheet always show to you possible connections with peripherials which you can do using Alternate functions of GPIO pins.
B.R.