200pA at 2V is 10G ohm resistance. That's well into the insulation resistance of many parts, not limiting to ceramic caps. The landing page of "low power" on Microchip.com only cites 9nA, so I would almost say this is a typo.. Maybe someone put an additive current for just some peripheral in there.. (like power-down +RTC +brown-out detector)
It's certainly not 0.2uA though. PIC16LF1503 is an older part and already has 20nA power-down current.
Regarding OP's question.. my first question is always: do you need low power or low energy (battery operation)?
They are not always the same. In particular low energy is an architecture problem, as many modern MCUs support a limited set of peripherals/operations in low power modes. It becomes real hard to do back-on-the-envelope calculations as estimations how much energy some project is going to consume.
I've looked at Ambiq micros before. Their CPU run modes are radically low power, but their peripheral set leaves a lot to be desired.
I'm now using a STM32U5 in a new design, as it supports on-demand clock requests to high-frequency peripherals, and DMA operations while the part is in a stop mode (sleep). MSP430 is also quite famous for supporting these power modes. And SiLabs also make quite a few..
But it depends on how much work you can put in for diminishing returns. I transitioned my design from a STM32L4 to STM32U5, and that lowered the average run power consumption from ~150uW to 70uW. Its a neat decrease, but given the amount of extra work put in, perhaps not worth it.
(But I'm in academia so there are plenty of other proportions out of whack

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